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Injection molding
Proper conditions and machine operations for molding Eastman
™
polymers are discussed in this section. It includes sections on
start-up, purging, use of regrind, and shutdown. The recommended
processing conditions are listed on the technical data sheet for
specific grades of Eastman
™
polymer. These data sheets can be
found online at www.eastman.com.
Molding conditions
Barrel and melt temperatures
The first consideration in setting barrel temperatures is how
much shot capacity will be used. Typically, if about half the
machine’s shot capacity is used in each shot, barrel temperatures
are set almost the same from back to front or slightly cooler at
the feed end. If the shot is small relative to machine capacity,
then temperatures are set significantly cooler at the feed end
to minimize degradation due to long residence times at high
temperatures. If the shot size is most of the machine’s capacity,
then flat or higher temperatures at the feed end are typically
used. These polymers often require a descending profile with
higher rear-zone setpoints to achieve proper screw recovery.
Another important factor is expected cycle time. For example,
if the expected cycle time is long because of limited mold cooling,
barrel temperatures should be lower. Different screws add
different amounts of shear heat, but it is common to see melt
temperatures 10°–20°C (20°–40°F) above the barrel settings.
Actual melt temperature should be checked with a needle
pyrometer. Melt temperature is best taken when the cycle is
established, and an on-cycle shot is caught in an insulated
container.
(CAUTION: Care must be exercised when taking samples of
HOT molten material.)
Melt temperature is the biggest factor in ease of filling the
mold. Typically, melt temperatures 5°–20°C (10°–30°F) above
the minimum temperature required to fill a part will give a good
processing window. Melt temperatures on the high end tend to
cause degradation and related problems.
Mold temperatures
Mold temperatures affect overall cycle, shrinkage, warpage, and
other characteristics of the molded part.
Copolyesters require colder molds than some other plastics;
therefore, antici pating cooling needs ahead of time (i.e., via tool
design) pays dividends in reduced cycle time and processability.
High mold temperatures can cause sticking. Even localized hot
spots where sticking might occur can extend the cycle.
Injection speed
To minimize gate blush, splay, or both, the fill speed used for
copolyesters is slower than for some other plastics. Machines
with fill speed programming capability are recommended.
Start the fill at a very slow speed, such as 10%–20% of available
capacity for the first 3%–5% of the shot, then increase to
40%–60% to complete the shot. An average fill rate of 50–250 g/s
(1.76–8.8 oz/s) is typical.
Screw speed
The screw should be run at the minimum rpm that will allow it
to recover 2–5 seconds before the mold opens. This minimizes
viscous heat generation, tends to make the melt more uniform,
and minimizes dead time.
Pack and hold
A common problem with direct sprue-gated parts is a shrinkage
void at the base of the sprue. Long hold times of 8–12 seconds
and lower hold pressures of 275–550 bar (4,000–8,000 psi)
(nozzle plastic pressure) will feed material to the sprue at a rate
that will eliminate voids but not overpack the sprue. Overall
cycle time does not have to be extended if the cooling timer is
decreased by the amount the hold timer is raised. A shrinkage
void can also form with a conventional runner at the junction
of the runner and sucker pin; this can be eliminated by using the
above methodology.
Cushion size
Cushion size should only be large enough to ensure the screw
does not hit bottom and the pack-and-hold pressures are
transmitted to the part. The cushion left at the end of the
pack-and-hold phase of the cycle is typically 3–13 mm
(0.125–0.5 in.), depending on machine size and injection
speed. Larger cushions can increase holdup time in the barrel
and contribute to degradation. Continued forward movement
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